Showing 8 results for Nanocrystalline
B. Alinejad1,, H. Sarpoolaky1,, A. Beitollahi1, S. Afshar2,
Volume 4, Issue 1 (6-2007)
Abstract
Abstract: Nanocrystalline MgAl2O4 spinel powder was synthesized using metal nitrates and a
polymer matrix-based composed of sucrose and polyvinyl alcohol (PVA). The precursor and the
calcined powders were characterized by simultaneous thermal analysis (STA), X-ray diffraction
(XRD), Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscopy
(SEM). According to XRD results, the inceptive formation temperature of spinel via this technique
was between 600°C and 700°C. The average crystallite size of calcined powder at 800°C for 2h
was in the range of 8-12nm. In addition, SEM micrograph showed that the synthesized powder had
a spherical morphology.
A.m. Rashidi, A. Amadeh,
Volume 7, Issue 2 (6-2010)
Abstract
Abstract:
nanocrystalline nickel samples with the grain size of ~25 nm were prepared via direct current electrodeposition and
aluminized for different durations by pack cementation method at 500
means of SEM, EDS and XRD techniques. According to results, short time aluminizing resulted in the formation of a
single aluminide layer whereas at long duration two distinct aluminide layers were formed. The growth kinetics of the
coating was non-parabolic at short times while it obeyed the parabolic law at long duration. The parabolic growth
rate constant of single phase coating formed on electrodeposited samples was about 30 ìm / h1/2 approximately 3 times
greater than the data reported for coarse grained nickel (8.4 ìm / h1/2). Meanwhile, the overall growth rate constant
was decreased to 11.7 ìm / h1/2, when double aluminide layers formed on nanocrystalline nickel.
In this research, aluminizing behavior of ultra fine-grained nickel was investigated. For this purpose,oC. The aluminide layers were examined by
Z. Ghaferi, K. Raeissi, M. A. Golozar,, A. Saatchi, S. Kabi,
Volume 7, Issue 4 (10-2010)
Abstract
Abstract:
current densities. Electrochemical impedance spectroscopy (EIS) results showed that the codeposition mechanism of
tungsten in Ni-W deposition is the reduction of tungsten oxide which changed to the reduction of tungsten-containing
ion complexes at higher current densities. In Co-W electrodeposition, the tungsten codeposition takes place via
reduction of tungsten oxide, although, the role of tungsten-containing complexes at higher current densities cannot be
ruled out. The surface morphology of Ni-W coatings was crack-free and was strongly dependent on deposition current
density. In addition, higher grain size and lower tungsten content were obtained by increasing the current density. In
Co-W coatings, no obvious variation in surface morphology was observed except for the fine cracks appeared at
higher current densities. In this system the grain size remained almost constant with increasing current density. The
microhardness values of Ni-W and Co-W coatings decreased due to the increase in the grain size and/or decrease in
tungsten content.
Ni-W and Co-W alloy nanocrystalline coatings were electrodeposited on copper substrate at different
M. R. Zamanzad-Ghavidel,, K. Raeissi, A. Saatchi,
Volume 9, Issue 2 (6-2012)
Abstract
Abstract: Nickel was electrodeposited onto copper substrates with high {111} and {400} peak intensities. The grain size of coatings deposited onto the copper substrate with a higher {111} peak intensity was finer. Spheroidized pyramid morphology was obtained at low current densities on both copper substrates. By increasing the deposition current density, grain size of the coating was increased for both substrates and eventually a mixed morphology of pyramids and blocks was appeared without further increase in grain size. This decreased the anodic exchange current density probably due to the decrease of surface roughness and led to a lower corrosion rate.
N. Mohammed, H. F. Dagher,
Volume 17, Issue 3 (9-2020)
Abstract
Thin films of meta-cinnabar mercuric sulfide (β-HgS) nanoparticles (NPs) was prepared by pulsed laser ablation (PLA) utilizing a pellet of cinnabar mercuric sulfide (α-HgS) was immersed in distilled water (DW). Q-switched Nd:YAG laser of 1064 nm wavelengths with repetition rate (1hz) and fluency (1.5 J/cm2) applied for ablation. Structural, morphological and particle sizes of the β-HgS NPs are invastigated by analyzing XRD, AFM, SEM and TEM measurements. Their crystal structure is transformed from hexagonal (wurtzite) of the α-HgS target material to cubic (zinc blende) β-HgS NPs. The optical properties of the β-HgS NPs are measured by UV–visible spectrophotometer. The direct band gap is calculated to be (2.45eV) of small particles (4-6.2nm) moreover, the band gap value of smallest particles (1-4nm) is (3.47eV) according to the optical transmission spectra
Mohammad Molaahmadi, Majid Tavoosi, Ali Ghasemi, Gholam Reza Gordani,
Volume 20, Issue 2 (6-2023)
Abstract
Investigation the structural and magnetic properties of nanocrystalline Co78Zr17B2Si1W2 alloy during melt spinning and annealing processes were the main goal of this study. In this regard, samples were prepared using vacuum induction melting, melt spinning and subsequent annealing. The specimens were evaluated using X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM). Based on results, nanocrystalline Co5Zr single phase with hard magnetic properties (Ms=29.5 emu/g and Hc=2.7 kOe) successfully formed during melt spinning process (at wheel speed of 40 m.s-1). The coercivity value of rapid solidified sample increased to about 3.2 kOe during annealing process up to 400°C. However, more increasing in annealing temperature lead to the transformation of non-equilibrium magnetic Co5Zr phase to stable Zr2Co11 phase, which has distractive effects on final magnetic properties.
Amit Bandekar, Pravin Tirmali, Paresh Gaikar, Shriniwas Kulkarni, Nana Pradhan,
Volume 21, Issue 1 (3-2024)
Abstract
The Mn-Zn ferrite with a composition of Mn0.25Mg0.08Cu0.25Zn0.42Fe2O4 has been synthesized in this study using the chemical sol-gel technique at a pH of 7. The sample was prepared and subsequently annealed at a temperature of 700°C. The nanocrystalline ferrite samples were subjected to characterization using X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Thermogravimetry (TG), and Differential thermal analysis (DTA). The findings of these observations are delineated and deliberated. The sample's phase composition was verified using X-ray diffraction examination. The crystalline size was determined using Scherrer's formula and was observed to be within the range of 20-75 nm. Two notable stretching bands were seen in the FTIR spectra within the range of 400-650 cm-1. The spinel structure of the produced nanoparticles was confirmed by these two bands. The magnetic characteristics of the powder were examined using a Vibrating Sample Magnetometer (VSM). The presence of M-H hysteresis loops suggests that the produced nanoparticles have superparamagnetic properties, as evidenced by their low coercive force, remanent magnetization, and saturation magnetization values.
Sandesh Jirage, Kishor Gaikwad, Prakash Chavan, Sadashiv Kamble,
Volume 21, Issue 1 (3-2024)
Abstract
The Cu2ZnSnS4 (CZTS) thin film is newly emerging semiconductor material in thin film solar cell industry. The CZTS composed of economical, common earth abundant elements. It has advantageous properties like high absorption coefficient and best band gap. Here we have applied low cost chemical bath deposition technique for synthesis of CZTS at low temperature, acidic medium and it’s characterization. The films were characterized by different techaniques like X-Ray diffraction, Raman, SEM, Optical absorbance, electrical conductivity and PEC study. The X-Ray diffraction, Raman scattering techniques utilized for structural study. The XRD revels kasterite phase and nanocrystalline nature of CZTS thin films. These results and its purity confirmed further by advanced Raman spectroscopy with 335 cm-1 major peak. The crystallite size which was found to be 50.19 nm. The optical absorbance study carried by use of UV-Visible spectroscopy analyses its band gap near about 1.5 eV and its direct type of absorption. The electrical conductivity technique gives p-type of conductivity. The scanning electron microscopy (SEM) study finds it’s rock like unique morphology. The EDS technique confirms its elemental composition and it’s fair stoichiometry. The analysis of PEC data revealed power conversion efficiency-PCE to 0.90%.
The Cu2ZnSnS4 (CZTS) thin film is newly emerging semiconductor material in thin film solar cell industry. The CZTS composed of economical, common earth abundant elements. It has advantageous properties like high absorption coefficient and best band gap. Here we have applied low cost chemical bath deposition technique for synthesis of CZTS at low temperature, acidic medium and it’s characterization. The films were characterized by different techaniques like X-Ray diffraction, Raman, SEM, Optical absorbance, electrical conductivity and PEC study. The X-Ray diffraction, Raman scattering techniques utilized for structural study. The XRD revels kasterite phase and nanocrystalline nature of CZTS thin films. These results and its purity confirmed further by advanced Raman spectroscopy with 335 cm-1 major peak. The crystallite size which was found to be 50.19 nm. The optical absorbance study carried by use of UV-Visible spectroscopy analyses its band gap near about 1.5 eV and its direct type of absorption. The electrical conductivity technique gives p-type of conductivity. The scanning electron microscopy (SEM) study finds it’s rock like unique morphology. The EDS technique confirms its elemental composition and it’s fair stoichiometry. The analysis of PEC data revealed power conversion efficiency-PCE to 0.90%.
